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understandingthesurfacestructureofmetalsinthe'strong-metalsupportinteraction'(SMSI)stateissummarized.

Literatureisreviewedontheadsorptionandreactionofawidevarietyofinanicmolecules(H2,O2,H2O,CO,CO2,N2,NH3,NOx,sulfur-andhalogen-containingmolecules,raregases)aswellasanicmolecules(carboxylicacids,alcohols,aldehydesandketones,alkynes,pyridineanditsderivates,silanes,methylhalides).TheapplicationofTiO2-basedsystemsinphoto-activedevicesisdiscussed,andtheresultsonUHV-basedphotocatalyticstudiesaresummarized.


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ThereviewendswithabriefconclusionandoutlookofTiO2-basedsurfacescienceforthefuture.

9.题名:TiO"2photocatalysisandrelatedsurfacephenomena

关 键 词:Titaniumdioxide,Titania,TiO2,Self-cleaningsurfaces,Superhydrophiliceffect,Aniondoping,Watersplitting,Environmentalcleaning

关 键 词:二氧化钛自清洁表面亲水性影响阴离子掺杂水裂解环境清洁SurfaceScienceReports,Volume63,Issue12,December2016,Pages515-582

作者:Fujishima,A.,Zhang,X.,Tryk,D.A.

摘 要:Thefieldofphotocatalysiscanbetracedbackmorethan80yearstoearlyobservationsofthechalkingoftitania-basedpaintsandtostudiesofthedarkeningofmetaloxidesincontactwithanicpoundsinsunlight.Duringthepast20years,ithasbeeanextremelywellresearchedfieldduetopracticalinterestinairandwaterremediation,self-cleaningsurfaces,andself-sterilizingsurfaces.Duringthesameperiod,therehasalsobeenastrongefforttousephotocatalysisforlight-assistedproductionofhydrogen.Thefundamentalaspectsofphotocatalysisonthemoststudiedphotocatalyst,titania,arestillbeingactivelyresearchedandhaverecentlybeequitewellunderstood.Themechanismsbywhichcertaintypesofanicpoundsaredeposedpletelytocarbondioxideandwater,forexample,havebeendelineated.However,certainaspects,suchasthephoto-inducedwettingphenomenon,remaincontroversial,withsomegroupsmaintainingthattheeffectisasimpleoneinwhichaniccontaminantsaredeposed,whileothergroupsmaintainthatthereareadditionaleffectsinwhichtheintrinsicsurfacepropertiesaremodifiedbylight.Duringthepastseveralyears,powerfultoolssuchassurfacespectroscopictechniquesandscanningprobetechniquesperformedonsinglecrystalsinultra-highvacuum,andultrafastpulsedlaserspectroscopictechniqueshavebeenbroughttobearontheseproblems,andnewinsightshavebeepossible.Quantumchemicalcalculationshavealsoprovidednewinsights.Newmaterialshaverecentlybeendevelopedbasedontitania,andthesensitivitytovisiblelighthasimproved.Thenewinformationavailableisstaggering,butwehopetoofferanoverviewofsomeoftherecenthighlights,aswellastoreviewsomeoftheoriginsandindicatesomepossiblenewdirections.

10.题名:Microstructure,martensitictransformationandmechanicalpropertiesofNi"5"0Mn"3"0Ga"2"0"-"xCu"xferromagicshapememoryalloys

关 键 词:Ni50Mn30Ga20xCux,Microstructure,Martensitictransformation,Mechanicalproperties

关 键 词:Ni50Mn30Ga20xCux,微观结构机械性能JournalofAlloysandCompounds,Volume538,October2016,Pages1-4

作者:Tan,C.L.,Dong,G.F.,Gao,L.,Sui,J.H.,Gao,Z.Y.,Cai,W.

摘 要:TheeffectofpartialsubstitutionofCuforGaonthemicrostructure,martensitictransformationandmechanicalpropertiesofNi50Mn30Ga20xCuxalloyswasinvestigatedbyopticalmicroscope(OM),differentscanningcalorimetry(DSC)andX-raydiffraction(XRD).TheresultsshowthattheNi50Mn30Ga20xCuxalloysexhibitthermoelasticmartensitictransformation.ThemartensitictransformationtemperaturesoftheNi50Mn30Ga20xCuxsampleincreaseremarkablywithincreaseofCucontent,whilethemartensitestructureofthesealloyschangesfrom7Mtonon-modulatedTmartensiteatroomtemperature.Inaddition,thepressivestrengthandfracturestrainofalloysareclearlyenhancedwithincreaseofCucontent,whichcanbeattributedtothestrengtheningofsolution.

11.题名:Carbonnanotube-polymerposites:Chemistry,processing,mechanicalandelectricalproperties

题名:碳纳米管聚合物复合材料:化学,加工,机械和电气性能

出处:ProgressinPolymerScience,Volume35,Issue3,March2016,Pages357-401

作者:Spitalsky,Z.,Tasis,D.,Papagelis,K.,Galiotis,C.

摘 要:Carbonnanotubeshavelongbeenrecognizedasthestiffestandstrongestman-madematerialknowntodate.Inaddition,theirhighelectricalconductivityhasrousedinterestintheareaofelectricalappliancesandmunicationrelatedapplications.However,duetotheirminisculesize,theexcellentpropertiesofthesenanostructurescanonlybeexploitediftheyarehomogeneouslyembeddedintolight-weigatricesasthoseofferedbyawholeseriesofengineeringpolymers.Wereviewthepresentstateofpolymernanopositesresearchinwhichthefillersarecarbonnanotubes.Inordertoenhancetheirchemicalaffinitytoengineeringpolymermatrices,chemicalmodificationofthegraphiticsidewallsandtipsisnecessary.Inthisreview,anextendedaccountofthevariouschemicalstrategiesforgraftingpolymersontocarbonnanotubesandthemanufacturingofcarbonnanotube/polymernanopositesisgiven.Themechanicalandelectricalpropertiestodateofawholerangeofnanopositesofvariouscar

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