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ons.Chemicalfunctionalizationofgrapheneenablesthismaterialtobeprocessedbysolvent-assistedtechniques,suchaslayer-by-layerassembly,spin-coating,andfiltration.Italsopreventstheagglomerationofsinglelayergrapheneduringreductionandmaintainstheinherentpropertiesofgraphene.Therefore,adetailedreviewontheadvancesofchemicalfunctionalizationofgrapheneispresented.Synthesisandcharacterizationofgraphenehavealsobeenreviewedinthecurrentarticle.Thefunctionalizationofgraphenecanbeperformedbycovalentandnoncovalentmodificationtechniques.Inbothcases,surfacemodificationofgrapheneoxidefollowedbyreductionhasbeencarriedouttoobtainfunctionalizedgraphene.Ithasbeenfoundthatboththecovalentandnoncovalentmodificationtechniquesareveryeffectiveinthepreparationofprocessablegraphene.However,theelectricalconductivityofthefunctionalizedgraphenehasbeenobservedtodecreasesignificantlyparedtopuregraphene.Moreover,thesurfaceareaofthefunctionalizedgraphenepreparedbycovalentandnon-covalenttechniquesdecreasessignificantlyduetothedestructivechemicaloxidationofflakegraphitefollowedbysonication,functionalizationandchemicalreduction.Inordertooveretheseproblems,severalstudieshavebeenreportedonthepreparationoffunctionalizedgraphenedirectlyfromgraphite(one-stepprocess).Inallthesecases,surfacemodificationofgraphenecanpreventagglomerationandfacilitatestheformationofstabledispersions.Surfacemodifiedgraphenecanbeusedforthefabricationofpolymernanoposites,super-capacitordevices,drugdeliverysystem,solarcells,memorydevices,transistordevice,biosensor,etc.

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有关论文范文主题研究: 图书馆类论文范文 大学生适用: 在职研究生论文、在职论文
相关参考文献下载数量: 87 写作解决问题: 如何怎么撰写
毕业论文开题报告: 标准论文格式、论文前言 职称论文适用: 论文发表、职称评中级
所属大学生专业类别: 如何怎么撰写 论文题目推荐度: 优质选题

4.题名:Graphenebasedmaterials:Past,presentandfuture

题名:石墨烯材料:过去,现在和未来ProgressinMaterialsScience,Volume56,Issue8,October2016,Pages1178-1271

作者:Singh,V.,Joung,D.,Zhai,L.,Das,S.,Khondaker,S.I.,Seal,S.

摘 要:Graphene,atwodimensionalmonoatomicthickbuildingblockofacarbonallotrope,hasemergedasanexoticmaterialofthe21stcentury,andreceivedworld-wideattentionduetoitsexceptionalchargetransport,thermal,optical,andmechanicalproperties.Grapheneanditsderivativesarebeingstudiedinnearlyeveryfieldofscienceandengineering.Recentprogresshasshownthatthegraphene-basedmaterialscanhaveaprofoundimpactonelectronicandoptoelectronicdevices,chemicalsensors,nanopositesandenergystorage.Theaimofthisreviewarticleistoprovideaprehensivescientificprogressofgraphenetodateandevaluateitsfutureperspective.Varioussynthesisprocessesofsinglelayergraphene,graphenenanoribbons,chemicallyderivedgraphene,andgraphene-basedpolymerandnanoparticlepositesarereviewed.Theirstructural,thermal,optical,andelectricalpropertieswerealsodiscussedalongwiththeirpotentialapplications.Thearticleconcludeswithabriefdiscussionontheimpactofgrapheneandrelatedmaterialsontheenvironment,itstoxicologicaleffectsanditsfutureprospectsinthisrapidlyemergingfield.

5.题名:Recentadvancesingraphenebasedpolymerposites

题名:石墨烯聚合物复合材料的新进展

出处:ProgressinPolymerScience,Volume35,Issue11,November2016,Pages1350-1375

作者:Kuilla,T.,Bhadra,S.,Yao,D.,Kim,N.H.,Bose,S.,Lee,J.H.

摘 要:Thispaperreviewsrecentadvancesinthemodificationofgrapheneandthefabricationofgraphene-basedpolymernanoposites.Recently,graphenehasattractedbothacademicandindustrialinterestbecauseitcanproduceadramaticimprovementinpropertiesatverylowfillercontent.Themodificationofgraphene/grapheneoxideandtheutilizationofthesematerialsinthefabricationofnanopositeswithdifferentpolymermatrixeshavebeenexplored.Differentanicpolymershavebeenusedtofabricategraphenefilledpolymernanopositesbyarangeofmethods.Inthecaseofmodifiedgraphene-basedpolymernanoposites,thepercolationthresholdcanbeachievedataverylowerfillerloading.Herein,thestructure,preparationandpropertiesofpolymer/graphenenanopositesarediscussedingeneralalongwithdetailedexamplesdrawnfromthescientificliterature.

6.题名:DifferentiationandquantificationofsurfaceaciditiesonMWCNTsbyindirectpotentiometrictitration

关 键 词:surfaceacidities,MWCNTs,CNTs

关 键 词:表面酸性,多壁碳纳米管,CNTs

出处:Carbon,Volume49,Issue9,August2016,Pages2978-2988

作者:Hanelt,S.,Orts-Gil,G.,Friedrich,J.F.,Meyer-Plath,A.

摘 要:Wet-chemicallyoxidizedcarbonnanotubes(CNTs)generallyexhibitbothcovalently-boundacidicfunctionalgroupsonthesurfaceandsurface-adsorbedacidicsubstances,i.e.carbonaceousCNTfragmentsfromtheoxidationprocedure.Directpotentiometrictitrationofoxidizablehighsurfaceareamaterialswithdynamicallydesorbingacidicfragmentsisslowandinaccurate.AdsorbedacidicfragmentsaredeprotonatedbysodiumhydroxideandformanionsinsolutionwhichisnotthecaseforcovalentlyboundacidicgroupsontheCNTs,sothefollowing

1 2 3 4 5 6 7 8 9 10

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